Density Functional Theory and X-ray Analysis of the Structural Variability in η5,η5,η1-Tris(ring) Rare Earth/Actinide Tetramethylpyrrolyl Complexes, (C5Me5)2M(NC4Me4)
Author:
Affiliation:
1. Department of Chemistry, University of California, Irvine, California 92697-2025, United States
Publisher
American Chemical Society (ACS)
Subject
Inorganic Chemistry,Physical and Theoretical Chemistry
Link
https://pubs.acs.org/doi/pdf/10.1021/ic300905r
Reference48 articles.
1. Chemistry of Tris(pentamethylcyclopentadienyl) f-Element Complexes, (C5Me5)3M
2. Facile Insertion of CO2 into Tetra- and Pentamethylcyclopentadienyl Lanthanide Moieties To Form (C5Me4RCO2)- Carboxylate Ligands (R = H, Me)
3. Comparative Reactivity of Sterically Crowded nf3 (C5Me5)3Nd and (C5Me5)3U Complexes with CO: Formation of a Nonclassical Carbonium Ion versus an f Element Metal Carbonyl Complex
4. Facile Triphenylborane-Based Syntheses of the Sterically Crowded Tris(pentamethylcyclopentadienyl) Complexes (C5Me5)3UMe and (C5Me5)3UCl
5. How Much Steric Crowding Is Possible in Tris(η5-pentamethylcyclopentadienyl) Complexes? Synthesis and Structure of (C5Me5)3UCl and (C5Me5)3UF1
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