Tuning the Dissociation of the Fe–PPh2(OR) Bond in Chiral-at-Metal Complexes [CpFe(Prophos)PPh2(OR)]PF6 (R = Me, Et, iPr, tBu). The Preparative Trick of N2 Bubbling-Reference-Cited by-同舟云学术

Tuning the Dissociation of the Fe–PPh2(OR) Bond in Chiral-at-Metal Complexes [CpFe(Prophos)PPh2(OR)]PF6 (R = Me, Et, iPr, tBu). The Preparative Trick of N2 Bubbling

Published:2013-08-21 Issue:17 Volume:32 Page:4904-4911
ISSN:0276-7333
Container-title:Organometallics
language:en
Short-container-title:Organometallics

Author:

Brunner Henri¹,Kurosawa Takaki²,Muschiol Manfred¹,Tsuno Takashi²,Balázs Gábor¹,Bodensteiner Michael¹

Affiliation:

1. Institut für Anorganische Chemie, Universität Regensburg, 93040 Regensburg, Germany

2. Department of Applied Molecular Chemistry, College of Industrial Technology, Nihon University, Chiba 275-8575, Japan

Publisher

American Chemical Society (ACS)

Subject

Inorganic Chemistry,Organic Chemistry,Physical and Theoretical Chemistry

Link

https://pubs.acs.org/doi/pdf/10.1021/om400631m

Reference31 articles.

1. Geometry of Coordinatively Unsaturated Two-Legged Piano Stool Complexes with 16 Valence Electrons: A Theoretical Study

2. The importance of interligand interactions to structure and reactivity of coordinatively unsaturated ruthenium and iron half-sandwich complexes—application of the TSC concept II

3. Ligand Dissociation: Planar or Pyramidal Intermediates?

4. Diastereomer Ratio of Products as a Mechanistic Probe in Epimerization and Ligand Exchange of Chiral-at-Metal [CpFe(Prophos)NCMe]X (X = I, PF6)

5. Spezifikation der molekularen Chiralität

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3. Kinetics of the SN1 Dissociation of Ligands L (Nitriles, Phosphines) in the Complexes [CpFe(P-P)L]PF6 with Variable Chelate Ring Size. A Surprising Bimolecular Substitution in the Nonchelate Complex [CpFe(PPh2Me)2L]PF6;Organometallics;2017-06-22

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5. Synthesis and reactivity of iron(II) hydride complexes containing diphenylphosphine ligands;Journal of Organometallic Chemistry;2015-08