Accessibility and Selective Stabilization of the Principal Spin States of Iron by Pyridyl versus Phenolic Ketimines: Modulation of the 6A1 ↔ 2T2 Ground-State Transformation of the [FeN4O2]+ Chromophore

Author:

Shongwe Musa S.1,Al-Zaabi Usama A.1,Al-Mjeni Faizah1,Eribal Carla S.2,Sinn Ekkehard2,Al-Omari Imaddin A.3,Hamdeh Hussein H.4,Matoga Dariusz5,Adams Harry6,Morris Michael J.6,Rheingold Arnold L.7,Bill Eckhard8,Sellmyer David J.9

Affiliation:

1. Department of Chemistry, College of Science, Sultan Qaboos University, PO Box 36, Al-Khod 123, Muscat, Sultanate of Oman

2. Department of Chemistry, Western Michigan University, Kalamazoo, Michigan 49008, United States

3. Department of Physics, College of Science, Sultan Qaboos University, PO Box 36, Al-Khod 123, Muscat, Sultanate of Oman

4. Department of Physics, Wichita State University, 1845 Fairmount St, Wichita, Kansas 67260, United States

5. Faculty of Chemistry, Jagiellonian University, Ingardena 3, 30-060 Kraków, Poland

6. Department of Chemistry, University of Sheffield, Sheffield S3 7HF, U.K.

7. Department of Chemistry and Biochemistry, University of California, San Diego, La Jolla, California 92093-0358, United States

8. Max-Planck-Institut für Bioanorganische Chemie, Stiftstrasse 34-36, 45470 Mülheim an der Ruhr, Germany

9. Department of Physics and Astronomy and Nebraska Center for Materials and Nanoscience, University of Nebraska, Lincoln, Nebraska 68588, United States

Publisher

American Chemical Society (ACS)

Subject

Inorganic Chemistry,Physical and Theoretical Chemistry

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