Calculation of Dramatic Differences in the Activation Energy of Phenyl Migratory Insertion in the Isomers of [Rh(PMe3)2Cl(CO)(Ph)H]: Important Effects from Both the Ligand trans to Ph and the Ligand trans to CO-Reference-Cited by-同舟云学术

Calculation of Dramatic Differences in the Activation Energy of Phenyl Migratory Insertion in the Isomers of [Rh(PMe3)2Cl(CO)(Ph)H]: Important Effects from Both the Ligand trans to Ph and the Ligand trans to CO

Published:2010-09-24 Issue:20 Volume:49 Page:9162-9168
ISSN:0020-1669
Container-title:Inorganic Chemistry
language:en
Short-container-title:Inorg. Chem.

Author:

Hasanayn Faraj¹,Abu-El-Ez Dina¹

Affiliation:

1. Department of Chemistry, American University of Beirut, Beirut, Lebanon

Publisher

American Chemical Society (ACS)

Subject

Inorganic Chemistry,Physical and Theoretical Chemistry

Link

https://pubs.acs.org/doi/pdf/10.1021/ic100198u

Reference76 articles.

1. Synthetic and Mechanistic Aspects of Inorganic Insertion Reactions. Insertion of Carbon Monoxide

2. Carbonyl-insertion reactions of square-planar complexes

3. Time resolved spectroscopic studies relevant to reactive intermediates in homogeneous catalysis. The migratory insertion reaction

4. Carbon monoxide insertion into transition metal-carbon sigma-bonds

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