Catalytic Asymmetric Synthesis of α,α,α-Trifluoromethylamines by the Copper-Catalyzed Nucleophilic Addition of Diorganozinc Reagents to Imines
Author:
Affiliation:
1. Département de Chimie, Université de Montréal, P. O. Box 6128, Station Downtown, Montréal (Québec), Canada H3C 3J7
Publisher
American Chemical Society (ACS)
Subject
Organic Chemistry,Physical and Theoretical Chemistry,Biochemistry
Link
https://pubs.acs.org/doi/pdf/10.1021/ol0607847
Reference32 articles.
1. Synthesis of optically pure (R)- and (S)-α-trifluoromethyl-alanine
2. Enantiomerically pure α-fluoroalkyl-α-amino acids: Synthesis of (R)-α-difluoromethyl-alanine and (S)-α-difluoromethyl-serine
3. Sulfinimines of trifluoropyruvate: Novel intermediates for chiral non racemic α-trifluoromethyl α-amino acids
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