Synthesis and Uses of exo-Glycals

Author:

Taillefumier Claude1,Chapleur Yves1

Affiliation:

1. Groupe SUCRES, UMR 7565 CNRS-UHP, Université Henri Poincaré-Nancy 1, BP 239, 54506 Nancy-Vandoeuvre, France

Publisher

American Chemical Society (ACS)

Subject

General Chemistry

Reference237 articles.

1. According to IUPAC recommendation, 2-Carb-17.2, “The term ‘glycal' is a non-preferred, trivial name for cyclic enol ether derivatives of sugars having a double bond between carbon atoms 1 and 2 of the ring. It should not be used or modified as a class name for monosaccharide derivatives having a double bond in any other position” (Pure Appl. Chem.1996,68, 1919−2008). The so-called ‘exo-glycals' are normally termed using an “anhydro-enitol”-based terminology. The term ‘C-glycosylidene' clearly indicates the double substitution at the anomeric centre and should be also used.

2. Unsaturated carbohydrates. Part IX. Synthesis of 2,3-dideoxy-α-D-erythro-hex-2-enopyranosides from tri-O-acetyl-D-glucal

3. C-glycoside synthesis by palladium-mediated glycal-aglycon coupling reactions

4. Glycals in Organic Synthesis: The Evolution of Comprehensive Strategies for the Assembly of Oligosaccharides and Glycoconjugates of Biological Consequence

5. Solid-Phase Synthesis of Oligosaccharides and Glycoconjugates by the Glycal Assembly Method:  A Five Year Retrospective

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