Iron(II) Cage Complexes of N-Heterocyclic Amide and Bis(trimethylsilyl)amide Ligands: Synthesis, Structure, and Magnetic Properties
Author:
Affiliation:
1. School of Chemistry, The University of Manchester, Oxford Road, Manchester M13 9PL, U.K.
Publisher
American Chemical Society (ACS)
Subject
Inorganic Chemistry,Physical and Theoretical Chemistry
Link
https://pubs.acs.org/doi/pdf/10.1021/ic102341a
Reference66 articles.
1. Synthesis of bis[bis(trimethylsilyl)amido]iron(II). Structure and bonding in M[N(SiMe3)2]2 (M = manganese, iron, cobalt): two-coordinate transition-metal amides
2. Three-coordinate iron complexes: x-ray structural characterization of the iron amide-bridged dimers [Fe(NR2)2]2 (R = SiMe3, C6H5) and the adduct Fe[N(SiMe3)2]2(THF) and determination of the association energy of the monomer Fe{N(SiMe3)2}2 in solution
3. Stable, Two-Coordinate, Open Shell (d0—d9) Transition Metal Complexes
4. Two-coordinate, nonlinear, crystalline d6 and d7 complexes: syntheses and structures of M{N(SiMePh2)2}2, M = Fe or Co
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