Organic Syntheses via Transition Metal Complexes. 118.1 Retro-Fischer Reaction Induced by a β-Imino Functionality of (Alkyl,ethoxy)carbene Complexes (M = W, Cr):  Efficient Access to C-Enamino and N-Enamino Carbene Complexes

Author:

Aumann Rudolf1,Fu Xiaolin1,Vogt Dominik1,Fröhlich Roland1,Kataeva Olga1

Affiliation:

1. Organisch-Chemisches Institut der Universität Münster, Corrensstrasse 40, D-48149 Münster, Germany

Publisher

American Chemical Society (ACS)

Subject

Inorganic Chemistry,Organic Chemistry,Physical and Theoretical Chemistry

Reference27 articles.

1. For the application of Fischer carbene complexes to organic syntheses see:  (a) Dötz, K.H.Angew. Chem.1984,96, 573−594;Angew. Chem., Int.Ed. Engl.1984,23, 587−608. (b) Wulff, W. D. InComprehensive OrganicSynthesis;Trost, B. M., Fleming, I., Eds.; Pergamon:  New York, 1991; Vol. 5, pp 1065−1113. (c) Wulff, W. D. InComprehensive OrganometallicChemistry II; Abel, E. W., Stone, F. G. A., Wilkinson, G., Eds.; Pergamon:  New York, 1995; Vol. 12, pp 469−547. (d) Doyle, M. P. InComprehensiveOrganometallic Chemistry II; Abel, E. W., Stone, F. G. A., Wilkinson, G. Eds.; Pergamon:  New York, 1995; Vol. 12, pp 387−420. (e) Wulff, W. D. InAdvances in Metal-Organic Chemistry; Liebeskind, L. S., Ed.; JAI Press:  Greenwich, CT, 1989; Vol. 1. (f) Harvey, D. F.; Sigano, D. M.Chem. Rev.1996,96(6), 271−288.(g) Frühauf, H.W.Chem. Rev.1997, 97, 523−596. (h) Schirmer, H.; Duetsch, M.; deMeijere, A.Angew. Chem.2000,112, 4124−4162;Angew. Chem., Int. Ed. Engl.1994,33, 3964−4002.

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