Mechanism of Oxidative Addition of Mercury(II) Compounds to Platinum(II)
Author:
Affiliation:
1. Department of Chemistry, The University of Western Ontario, London, Ontario N6A 5B7, Canada
Publisher
American Chemical Society (ACS)
Subject
Inorganic Chemistry,Physical and Theoretical Chemistry
Link
https://pubs.acs.org/doi/pdf/10.1021/ic001145%2B
Reference9 articles.
1. Reactivity of [M(C∧P)(acac-O,O‘)] [M = Pt, Pd; C∧P = CH2-C6H4-P(o-tolyl)2-κC,P; acac = 2,4-pentanedionato] toward HgX2 (X = Br, I, CH3COO, CF3COO). New Polynuclear Complexes Containing Pt−Hg Bonds. Molecular Structures of [{Pt(C∧P)(acac-O,O‘)- HgBr(μ-Br)}2(μ-HgBr2)], an Unprecedented Square-Planar Bromomercurate Complex, and [{Pt(C∧P)(μ-O2CCH3)2Hg(μ3-acac2--κC3,O)Hg(O2CCH3-κO)}· CHCl3]2, the First Complex Containing Asymmetric Dimercurated Acetylacetone
2. Crystal structure and molecular geometry of a square-pyramidal platinum(II) complex [{2,6-(Me2NCH2)2C6H3}Pt(.mu.-{(p-tol)NC(H)N(i-Pr)})HgBrCl] containing a PtII-to-HgII donor bond
3. Reactivity of [M(C∧P)(S2CNMe2)] [M = Pt, Pd; C∧P = CH2−C6H4−P(o-tolyl)2-κC,P] toward Mercury(II) Carboxylates. X-ray Molecular Structures of [Pt(C∧P)(S2CNMe2)(O2CCF3)Hg(O2CCF3)] and [Pd(S2CNMe2){μ-P(o-tolyl)2−C6H4−CH2−}(μ-O2CCH3)Hg(O2CCH3)]
4. Mechanisms of d8 organometallic reactions involving electrophiles and intramolecular assistance by nucleophiles
5. Mechanisms of methyl transfer reactions from methylplatinum(II) complexes
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