Experimental Evidence for Negative Hyperconjugation as a Component of the Polar Effect: Variation of the Ease of α-Sulfonyl Carbanion Formation with the Orientation of a β-Alkoxy Substituent-Reference-Cited by-同舟云学术

Experimental Evidence for Negative Hyperconjugation as a Component of the Polar Effect: Variation of the Ease of α-Sulfonyl Carbanion Formation with the Orientation of a β-Alkoxy Substituent

Published:2000-10-01 Issue:42 Volume:122 Page:10308-10324
ISSN:0002-7863
Container-title:Journal of the American Chemical Society
language:en
Short-container-title:J. Am. Chem. Soc.

Author:

King James F.¹,Rathore Rajendra¹,Guo Zhenrong¹,Li Manqing¹,Payne Nicholas C.¹

Affiliation:

1. Contribution from the Department of Chemistry, The University of Western Ontario, London, Ontario, Canada N6A 5B7

Publisher

American Chemical Society (ACS)

Subject

Colloid and Surface Chemistry,Biochemistry,General Chemistry,Catalysis

Link

https://pubs.acs.org/doi/pdf/10.1021/ja001320l

Reference83 articles.

1. (a) Hine, J.Physical Organic Chemistry, 2nd ed.; McGraw-Hill: New York, 1962; p 83.

2. (b) Lowry, T. H.; Richardson, K. S.Mechanism and Theoryin Organic Chemistry, 3rd ed.; Harper and Row: New York, 1987; p 152n.

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