Cluster Fragmentation and Facile Cleavage of Phenyl Groups from the SnPh3 Ligand in Reactions of Os3(CO)11(SnPh3)(μ-H) with CO and HSnPh3
Author:
Affiliation:
1. Department of Chemistry and Biochemistry, University of South Carolina, Columbia, South Carolina 29208
Publisher
American Chemical Society (ACS)
Subject
Inorganic Chemistry,Organic Chemistry,Physical and Theoretical Chemistry
Link
https://pubs.acs.org/doi/pdf/10.1021/om0603262
Reference36 articles.
1. Diphosphine Isomerization and C−H and P−C Bond Cleavage Reactivity in the Triosmium Cluster Os3(CO)10(bpcd): Kinetic and Isotope Data for Reversible Ortho Metalation and X-ray Structures of the Bridging and Chelating Isomers of Os3(CO)10(bpcd) and the Benzyne-Substituted Cluster HOs3(CO)8(μ3-C6H4)[μ2,η1-PPhCC(PPh2)C(O)CH2C(O)]
2. Oxidative addition reactions in cluster complexes of osmium: Intracluster reactions of benzyne and a novel 'phenyl' complex
3. Oxidative addition reactions of triphenylphosphine with dodecacarbonyltriosmium(0) : benzyne-, phenyl-, and related complexes of osmium
4. Transition-metal-mediated phosphorus-carbon bond cleavage and its relevance to homogeneous catalyst deactivation
5. Platinum-tin reforming catalysts I. The oxidation state of tin and the interaction between platinum and tin
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