Photochemical Reaction of Mo(CO)6 with Et2GeH2: NMR and DFT Studies of Reaction Products; Crystal Structure of a Novel Complex [{Mo(μ-η2-H−GeEt2)(CO)4}2]-Reference-Cited by-同舟云学术

Photochemical Reaction of Mo(CO)6 with Et2GeH2: NMR and DFT Studies of Reaction Products; Crystal Structure of a Novel Complex [{Mo(μ-η2-H−GeEt2)(CO)4}2]

Published:2009-09-30 Issue:20 Volume:28 Page:5857-5865
ISSN:0276-7333
Container-title:Organometallics
language:en
Short-container-title:Organometallics

Author:

Zyder Magdalena¹,Kochel Andrzej¹,Handzlik Jarosław²,Szymańska-Buzar Teresa¹

Affiliation:

1. Faculty of Chemistry, University of Wrocław, ul. F. Joliot-Curie 14, 50-383 Wrocław, Poland

2. Institute of Organic Chemistry and Technology, Cracow University of Technology, ul. Warszawska 24, 31-155 Kraków, Poland

Publisher

American Chemical Society (ACS)

Subject

Inorganic Chemistry,Organic Chemistry,Physical and Theoretical Chemistry

Link

https://pubs.acs.org/doi/pdf/10.1021/om900299k

Reference70 articles.

1. Fundamentals of H2 Binding and Reactivity on Transition Metals Underlying Hydrogenase Function and H2 Production and Storage

2. Synthesis and Crystal Structures of the First Stable Mononuclear Dihydrogermyl(hydrido) Platinum(II) Complexes

3. Preparation and Structure of a New Dipalladium Complex with Bridging Diphenylgermyl Ligands. Diverse Reactivities of Pd(PCy3)2 and Pt(PCy3)2 toward Ph2GeH2

4. Silane Complexes of Electrophilic Metal Centers

5. Unexpected Formation of Polydentate Phosphinoalkyl−Silyl and −Germyl Ligands from Reaction of [MoH4(Ph2PCH2CH2PPh2)2] with Organosilanes and Organogermanes: Novel Activation of Mo−H, E−H (E = Si, Ge), and C−H Bonds in the Same System

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