Asymmetric Hydrogenation. Dimerization of Solvate Complexes: Synthesis and Characterization of Dimeric [Rh(DIPAMP)]22+, a Valuable Catalyst Precursor
Author:
Affiliation:
1. Leibniz Institute for Catalysis at the University of Rostock, Albert-Einstein-Strasse 29A, D-18059 Rostock, Germany
2. Institute for Biochemistry, Felix-Hausdorff-Strasse 4, D-17489 Greifswald, Germany
Publisher
American Chemical Society (ACS)
Subject
Inorganic Chemistry,Organic Chemistry,Physical and Theoretical Chemistry
Link
https://pubs.acs.org/doi/pdf/10.1021/om801199q
Reference35 articles.
1. Novel coordination chemistry and catalytic properties of cationic 1,2-bis(diphenylphosphino)ethanerhodium(I) complexes
2. The Inhibiting Influence of Aromatic Solvents on the Activity of Asymmetric Hydrogenations We would like to thank the Deutsche Forschungsgemeinschaft as well as the Fonds der Chemischen Industrie for their generous support of this work. We are also indebted to Prof. Dr. U. Rosenthal and Dr. D. Selent for helpful discussions. Franz Hein prepared bis(η6-arene)-chromium(I)-complex cations already in 1919; their true structure as hexahapto complexes was only realized more than 35 years later.
3. Asymmetric catalysis. Asymmetric catalytic intramolocular hydrosilation and hydroacylation
4. Homogeneous catalysis. Mechanism of catalytic hydroacylation: the conversion of 4-pentenals to cyclopentanones
5. Asymmetric catalysis. Production of chiral diols by enantioselective catalytic intramolecular hydrosilation of olefins
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