σ−π* Electronic Transition of the Di- and Trinuclear Complexes Ru(E)(E‘)(CO)2(iPr-DAB): Resonance Raman, Electronic Absorption, Emission, and Density Functional Study (E = Me, SnPh3, M(CO)5; E‘ = M(CO)5; M = Mn, Re; iPr-DAB = N,N‘-Diisopropyl-1,4-diaza-1,3-butadiene)-Reference-Cited by-同舟云学术

σ−π* Electronic Transition of the Di- and Trinuclear Complexes Ru(E)(E‘)(CO)2(iPr-DAB): Resonance Raman, Electronic Absorption, Emission, and Density Functional Study (E = Me, SnPh3, M(CO)5; E‘ = M(CO)5; M = Mn, Re; iPr-DAB = N,N‘-Diisopropyl-1,4-diaza-1,3-butadiene)

Published:1997-05-01 Issue:10 Volume:16 Page:2055-2062
ISSN:0276-7333
Container-title:Organometallics
language:en
Short-container-title:Organometallics

Author:

Aarnts Maxim P.¹,Wilms Maikel P.¹,Stufkens Derk J.¹,Baerends Evert Jan²,Vlček Antonín³

Affiliation:

1. Anorganisch Chemisch Laboratorium, J. H. van't Hoff Research Institute, Universiteit van Amsterdam, Nieuwe Achtergracht 166, 1018 WV Amsterdam, The Netherlands

2. Afdeling Theoretische Chemie, Vrije Universiteit, De Boelelaan 1083, 1081 HV Amsterdam, The Netherlands

3. J. Heyrovský Institute of Physical Chemistry, Academy of Sciences of the Czech Republic, Dolejškova 3, 182 23 Prague, Czech Republic, and Department of Chemistry, Queen Mary and Westfield College, University of London, London E1 4NS, U.K.

Publisher

American Chemical Society (ACS)

Subject

Inorganic Chemistry,Organic Chemistry,Physical and Theoretical Chemistry

Link

https://pubs.acs.org/doi/pdf/10.1021/om9608667

Reference44 articles.

1. Influence of X and R on the Emission of [Ru(X)(R)(CO)2(.alpha.-diimine)] (X = Halide, Mn(CO)5; R = alkyl): Change of Character of the Lowest-Excited State from MLCT (X = Cl) to XLCT (X = I) and .sigma.b.pi. (X = Mn(CO)5)

2. Time-Resolved Absorption, Infrared, and Resonance Raman Spectra of the Complexes [Ru(X)(R)(CO)2(.alpha.-Diimine)] (X = Halide; R = Alkyl): Influence of X on the Charge Transfer Character of the Lowest Excited State

3. Synthesis and spectroscopic properties of Re(R)(CO)3(α-diimine) (R  alkyl; α-diimine  R′-pyCa, R′-DAB) complexes. Crystal structure of Re(Me) (CO)3 (iPr-DAB)

4. First Direct Structural Information on a Reactive .sigma..pi.* Excited State: Time-Resolved UV-Vis and IR Spectroscopic Study of Re(benzyl)(CO)3(iPr-DAB)

5. Photochemistry of metal-metal bonds

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