Synthesis and Structural Comparison of TpiPr2Rh[cis-1,2-bis(diphenylphosphino)ethene]: Factors Determining Hapticity (κ2 vs κ3) of the TpiPr2 Ligand in TpiPr2Rh(diphosphine) Complexes
Author:
Affiliation:
1. Chemical Resources Laboratory, Tokyo Institute of Technology, 4259 Nagatsuta, Midori-ku, Yokohama 226-8503, Japan
Publisher
American Chemical Society (ACS)
Subject
Inorganic Chemistry,Organic Chemistry,Physical and Theoretical Chemistry
Link
https://pubs.acs.org/doi/pdf/10.1021/om0003640
Reference6 articles.
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2. (b) Trofimenko, S.Scorpionates: The Coordination Chemistry of Polypyrazolylborate Ligands; Imperial College Press: London, England, 1999.
3. Stereochemically nonrigid bis(olefin)rhodium poly(1-pyrazolyl)borato complexes. 1. Synthesis and conversion into new rhodium(I) and rhodium(III) complexes. The crystal and molecular structure of [tetrakis(1-pyrazolyl)borato]diiodocarbonylrhodium(III) methylene chloride solvate
4. Synthesis and Structure Determination of Rh−diene Complexes with the Hydridotris(3,5-diisopropylpyrazolyl)borate Ligand, TpiPrRh(diene) (diene = cod, nbd): Dependence of the ν(B−H) Values on the Hapticity of the TpiPr Ligand (κ2 vs κ3)1
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