Effects of Complexation with 18-Crown-6 on the Hypernucleofugality of Phenyl-λ3-iodanyl Groups. Synthesis of Vinyl-λ3-iodane·18-Crown-6 Complex
Author:
Affiliation:
1. Faculty of Pharmaceutical Sciences, University of Tokushima, 1-78 Shomachi, Tokushima 770-8505, Japan, and Rigaku Corporation, 3-9-12 Matsubara, Akishima, Tokyo 196-8666, Japan
Publisher
American Chemical Society (ACS)
Subject
Organic Chemistry,Physical and Theoretical Chemistry,Biochemistry
Link
https://pubs.acs.org/doi/pdf/10.1021/ol050858z
Reference24 articles.
1. Solvolysis of Cyclohexenyliodonium Salt, a New Precursor for the Vinyl Cation: Remarkable Nucleofugality of the Phenyliodonio Group and Evidence for Internal Return from an Intimate Ion-Molecule Pair
2. Inversion of configuration in nucleophilic vinylic substitutions of (E)-.beta.-alkylvinyliodonium tetrafluoroborates with halides
3. In-Plane Vinylic SN2 Substitution and Intramolecular β Elimination of β-Alkylvinyl(chloro)-λ3-iodanes
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