1. Contribution from the Dipartimento di Chimica IFM, Università di Torino and NIS, Nanostructured Interfaces and Surfaces Centre of Excellence,via P. Giuria 7, 10125, Torino, Italy, Laboratory for Spectroscopy in Biophysics and Catalysis, Department of Physics, University of Antwerp, Universiteitsplein 1, B-2610 Wilrijk, Belgium, and Laboratory of Adsorption and Catalysis, Department of Chemistry, University of Antwerp, Universiteitsplein 1, B-2610 Wilrijk, Belgium