Preparation and Reactions of [CpOs(CH3CN)3]+. A Useful Synthetic Intermediate for the Preparation of CpOsL3 Compounds
Author:
Affiliation:
1. Department of Chemistry, University of Minnesota, Minneapolis, Minnesota 55455
Publisher
American Chemical Society (ACS)
Subject
Inorganic Chemistry,Physical and Theoretical Chemistry
Link
https://pubs.acs.org/doi/pdf/10.1021/ic9601504
Reference46 articles.
1. Synthesis and Characterization of (C5Me5)2Os2Br4 and the Osmium Polyhydride (C5Me5)OsH5: A New Synthetic Entry into Mono(pentamethylcyclopentadienyl)osmium Chemistry
2. New hydride, alkyl, aryl, halide, alkene, alkyne, acetylide, and vinylidene members of the (.eta.5-C5Me5)Os(CO)(L)X family. Crystal and molecular structures of [(.eta.5-C5Me5)Os(CO)3][BF4] and [(.eta.5-C5Me5)Os(CO)(PPh3)(:C:C(tert-Bu)H)][BF4]
3. Oxidative addition reactions of compounds of the type (.eta.5-C5Me5)Os(CO)LR (L = CO, PMe2Ph; R = alkyl). The role of oxidized intermediates in electrophilic cleavage reactions of osmium-carbon .sigma.-bonds
4. Übergangsmetall-substituierte acylphosphane und phosphaalkene
5. Oxidative addition reactions of Cp*Os(CO)(PMe2Ph)Me (Cp* = η5-C5Me5). Isolation of intermediates during alkyl—metal electrophilic cleavage reactions
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