Examination of Metal−Silicon Bonding through Structural and Theoretical Studies of an Isostructural Set of Five-Coordinate Silyl Complexes, Os(SiR3)Cl(CO)(PPh3)2 (R = F, Cl, OH, Me)
Author:
Affiliation:
1. Department of Chemistry, The University of Auckland, Private Bag 92019, Auckland, New Zealand
Publisher
American Chemical Society (ACS)
Subject
Inorganic Chemistry,Organic Chemistry,Physical and Theoretical Chemistry
Link
https://pubs.acs.org/doi/pdf/10.1021/om970580h
Reference32 articles.
1. A silyliron compound; an Fe-Si ? bond
2. Electronic structure of transition metal-silicon bonds. Valence photoelectron spectra of (.eta.5-C5H5)Fe(CO)2L complexes (L = SiCl3, Si(CH3)3)
3. UPS Study of Compounds with Metal−Silicon Bonds: M(CO)nSiCl3 (M = Co, Mn; n = 4, 5) and Fe(CO)4(SiCl3)2
4. Coordinatively unsaturated σ-aryl complexes of ruthenium(II) and osmium(II)
5. The diosmium tetrahydroxydisiloxane, [OsCl(CO)(PPh3)2Si(OH)2]2O, from the coordinatively unsaturated trihydroxysilyl complex, Os(Si[OH]3)Cl(CO)(PPh3)2
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