Regio- and Enantioselective Pd-Catalyzed Allylic Alkylation of Ketones through Allyl Enol Carbonates
Author:
Affiliation:
1. Department of Chemistry, Stanford University, Stanford, California 94305-5080
Publisher
American Chemical Society (ACS)
Subject
Colloid and Surface Chemistry,Biochemistry,General Chemistry,Catalysis
Link
https://pubs.acs.org/doi/pdf/10.1021/ja043472c
Reference14 articles.
1. (a) Enders, D. inAsymmetric Synthesis: Stereodifferentiating AdditionReactions, Part B; Morrison, J. D., Ed; Academic: Orlando, FL, 1984; Vol. 3, p 275. For a recent application see: (b) Enders, D.; Voith, M.; Ince, S. J.Synthesis2002, 1775.
2. Stereoselective Reactions. Part 31: Catalytic Asymmetric Alkylation of Achiral Lithium Enolates Using a Chiral Tetradentate Amine in the Presence of an Achiral Bidentate Amine
3. 1,1,4,7,10-10-Hexamethyltriethylenetetramine: a reagent to enhance the rate of alkylation reaction of the lithium enolate of 1-tetralone with alkyl halides
4. Rate Enhancement with High Ratio of the Monoalkylated Product to the Dialkylated Product in the Alkylation of the Lithium Enolate of 1-Tetralone with Reactive Alkyl Halides.
5. Palladium-Catalyzed Asymmetric Alkylation of Ketone Enolates
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