Characterizing Traditional and Chlorine-Shared Halogen Bonds in Complexes of Phosphine Derivatives with ClF and Cl2
Author:
Affiliation:
1. Instituto de Química Médica (IQM-CSIC), Juan de la Cierva, 3, E-28006 Madrid, Spain
2. Department of Chemistry, Youngstown State University, Youngstown, Ohio 44555, United States
Publisher
American Chemical Society (ACS)
Subject
Physical and Theoretical Chemistry
Link
https://pubs.acs.org/doi/pdf/10.1021/jp503436f
Reference50 articles.
1. The structure of triphenylphosphorus–diiodine, Ph3PI2, the first crystallographically characterised dihalogen derivative of a tertiary phosphine
2. The structure of triphenylphosphorus–dibromine, the first crystallographically characterised bromophosphorane, a compound which has the novel four-coordinate molecular Ph3P–Br–Br geometry
3. The reaction of some tertiary phosphines with two mole equivalents of diiodine to produce the iodophosphonium triiodides [R3PI]I3; influence of R in causing subtle variations in solid state structures
4. The reaction of tertiary aryl phosphites with diiodine at ambient temperatures; structural characterisation of the tertiary phosphite tetraiodides (PhO)3PI4, (4-MeC6H4O)3PI4 and (2,4-But2C6H3O)3PI4
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