Reactions of a Dihydrogen Complex with Terminal Alkynes: Formation of Osmium−Carbyne and −Carbene Derivatives with the Hydridotris(pyrazolyl)borate Ligand-Reference-Cited by-同舟云学术

Reactions of a Dihydrogen Complex with Terminal Alkynes: Formation of Osmium−Carbyne and −Carbene Derivatives with the Hydridotris(pyrazolyl)borate Ligand

Published:2008-06-28 Issue:14 Volume:27 Page:3547-3555
ISSN:0276-7333
Container-title:Organometallics
language:en
Short-container-title:Organometallics

Author:

Castro-Rodrigo Ruth¹,Esteruelas Miguel A.¹,López Ana M.¹,Oñate Enrique¹

Affiliation:

1. Departamento de Química Inorgánica, Instituto de Ciencia de Materiales de Aragón, Universidad de Zaragoza-CSIC, 50009 Zaragoza, Spain

Publisher

American Chemical Society (ACS)

Subject

Inorganic Chemistry,Organic Chemistry,Physical and Theoretical Chemistry

Link

https://pubs.acs.org/doi/pdf/10.1021/om800248e

Reference104 articles.

1. Esteruelas, M. A. and López, A. M.InRecent Advances in Hydride Chemistry;Peruzzini, M. and Poli, R., Eds.Elsevier:Amsterdam, 2001; Chapter 7, pp189−248

2. Synthesis of new hydride-carbyne and hydride-vinylcarbyne complexes of osmium(II) by reaction of OsH2Cl2(P-iso-Pr3)2 with terminal alkynes

3. Osmium Converts Terminal Olefins to Carbynes: α-Hydrogen Migration Redox Isomers with Reversed Stability for Ruthenium and for Osmium

4. Carbynehydrido- and Vinylidenehydridoosmium Complexes with Os(PCy3)2 as a Molecular Unit

5. Reactions of the Dihydrogen Complex OsCl2(.eta.2-H2)(CO)(PiPr3)2 with Terminal Alkynes: Synthesis of Carbene, Vinylcarbene, and .mu.-Bis-carbene Osmium (II) Derivatives

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