Experimental and Computational Studies of Binding of Dinitrogen, Nitriles, Azides, Diazoalkanes, Pyridine, and Pyrazines to M(PR3)2(CO)3 (M = Mo, W; R = Me, iPr).
Author:
Affiliation:
1. Chemistry Department, Brookhaven National Laboratory, Upton, New York 11973
2. Chemistry Division, MS-J514, Los Alamos National Laboratory, Los Alamos, New Mexico 87545
3. Department of Chemistry, University of Miami, Coral Gables, Florida 33146
Publisher
American Chemical Society (ACS)
Subject
Inorganic Chemistry,Physical and Theoretical Chemistry
Link
https://pubs.acs.org/doi/pdf/10.1021/ic900764e
Reference76 articles.
1. Metal Dihydrogen and σ-Bond Complexes
2. Five-co-ordinate molybdenum and tungsten complexes, [M(CO)3(PCy3)2], which reversibly add dinitrogen, dihydrogen, and other small molecules
3. Comparison of Thermodynamic and Kinetic Aspects of Oxidative Addition of PhE−EPh (E = S, Se, Te) to Mo(CO)3(PR3)2, W(CO)3(PR3)2, and Mo(N[tBu]Ar)3 Complexes. The Role of Oxidation State and Ancillary Ligands in Metal Complex Induced Chalcogenyl Radical Generation
4. Oxidative Addition of Thiols, Disulfides, Iodine, and Hydrogen Iodide to W(CO)3(PiPr3)2. Preparation of Stable 17-Electron Tungsten Thiolate Radicals from Complexes with Weak W-H Bonds
5. Equilibrium Isotope Effect for the W(CO)3(PCy3)2(H)2/W(Co)3(PCy3)2(η2-H2) Tautomeric Equilibrium: A Nuclear Dynamics Variable Representation Study
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