Reactivity toward Neutral N- and P-Donor Ligands of Eight-Membered Palladacycles Arising from Monoinsertion of Alkynes into the Pd–C Bond of Orthopalladated Homoveratrylamine and Phentermine. A New Example of the Transphobia Effect-Reference-Cited by-同舟云学术

Reactivity toward Neutral N- and P-Donor Ligands of Eight-Membered Palladacycles Arising from Monoinsertion of Alkynes into the Pd–C Bond of Orthopalladated Homoveratrylamine and Phentermine. A New Example of the Transphobia Effect

Published:2013-12-06 Issue:1 Volume:33 Page:33-39
ISSN:0276-7333
Container-title:Organometallics
language:en
Short-container-title:Organometallics

Author:

Oliva-Madrid María-José¹,García-López José-Antonio¹,Saura-Llamas Isabel¹,Bautista Delia²,Vicente José¹

Affiliation:

1. Grupo de Química Organometálica, Departamento de Química Inorgánica, Universidad de Murcia, Apartado 4021, 30071 Murcia, Spain

2. SAI, Universidad de Murcia, Apartado 4021, 30071 Murcia, Spain

Publisher

American Chemical Society (ACS)

Subject

Inorganic Chemistry,Organic Chemistry,Physical and Theoretical Chemistry

Link

https://pubs.acs.org/doi/pdf/10.1021/om401090b

Reference76 articles.

1. ORTHO-PALLADATION OF PRIMARY AMINES: THE MYTH DISPELLED

2. Insertion of Isocyanides, Isothiocyanates, and Carbon Monoxide into the Pd−C Bond of Cyclopalladated Complexes Containing Primary Arylalkylamines of Biological and Pharmaceutical Significance. Synthesis of Lactams and Cyclic Amidinium Salts Related to the Isoquinoline, Benzo[g]isoquinoline, and β-Carboline Nuclei

3. Reactivity of Eight-Membered Palladacycles Arising from Monoinsertion of Alkynes into the Pd–C bond of Ortho-Palladated Phenethylamines toward Unsaturated Molecules. Synthesis of Dihydro-3-Benzazocinones, N7-amino Acids, N7-amino Esters, and 3-Benzazepines

4. Reactivity of cyclopalladated complexes. Part 5. Insertion reactions of diphenylacetylene, 1-phenylprop-1-yne, and hexafluorobut-2-yne with cyclopalladated compounds. Crystal and molecular structure of chloro{3–4-η-4-[(2-dimethylaminomethyl)phenyl]-1,4-dimethyl-2,3-diphenylbuta-1,3-dienyl-C1N}palladium(II) and bromo{3–4-η-4-[(2-dimethylaminomethyl)phenyl]-2,4-dimethyl-1,3-diphenylbuta-1,3-dienyl-C1N}-palladium(II)

5. Reaction of cyclopalladated compounds. 15. Controlled synthesis of heterocyclic compounds through ring enlargement by alkyne insertions into the palladium-carbon bonds of cyclopalladated amines followed by ring closure

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