Bis(oxazolinyl)phenylrhodium(III) Aqua Complexes:  Synthesis, Structure, Enantioselective Allylation of Aldehydes, and Mechanistic Studies

Author:

Motoyama Yukihiro1,Okano Masanori1,Narusawa Hiroki1,Makihara Nobuyuki1,Aoki Katsuyuki1,Nishiyama Hisao1

Affiliation:

1. School of Materials Science, Toyohashi University of Technology, Tempaku-cho, Toyohashi, Aichi 441-8580, Japan

Publisher

American Chemical Society (ACS)

Subject

Inorganic Chemistry,Organic Chemistry,Physical and Theoretical Chemistry

Reference51 articles.

1. Reviews:  (a) Courtois, G.; Miginiac, L.J. Organomet. Chem.1974,69, 1. (b) Biellmann, J. F.; Ducep, J. B.Org. React.1982,27, 1. (c) Hoffmann, R. W.Angew. Chem., Int. Ed. Engl.1982,21, 555. (d) Roush, W. R. InComprehensive Organic Synthesis; Trost, B. M., Fleming, I., Heathcock, C. H., Eds.; Pergamon Press:  Oxford, U.K., 1991; Vol. 2, p 1. (e) Yamamoto, Y.; Asao, N.Chem. Rev.1993,93, 2207. (f) Bach, T.Angew.Chem., Int. Ed. Engl.1994,33, 417. (g) Hoveyda, A. H.; Morken, J. P.Angew. Chem., Int. Ed. Engl.1996,35, 1262.

2. Asymmetric carbon-carbon bond formation via .beta.-allyldiisopinocampheylborane. Simple synthesis of secondary homoallylic alcohols with excellent enantiomeric purities

3. Chiral Allylic and Allenic Stannanes as Reagents for Asymmetric Synthesis

4. Allylbutyltin halides (CH2CHCH2)SnBu3−nCln (n = 0, 1, 2, 3). Preparation, carbon-13 NMR characterization and allylstannylation ability towards ketones and aldehydes

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