Proof by EPR Spectroscopy that the Unpaired Electron in an Os27+ Species Is in a δ* Metal-based Molecular Orbital
Author:
Affiliation:
1. Department of Chemistry, P.O. Box 30012, Texas A&M University, College Station, Texas 77842-3012 and
2. Department of Chemistry, Dittmer Building, Florida State University, Tallahassee, Florida, 32306-4390
Publisher
American Chemical Society (ACS)
Subject
Inorganic Chemistry,Physical and Theoretical Chemistry
Link
https://pubs.acs.org/doi/pdf/10.1021/ic902087e
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1. Mononuclear and Polynuclear Chemistry of Rhenium (III): Its Pronounced Homophilicity
2. Multiple Bonds Between Metal Atoms
3. A Highly Reduced V23+ Unit with a Metal−Metal Bond Order of 3.5
4. New Chemistry of the Triply Bonded Divanadium (V24+) Unit and Reduction to an Unprecedented V23+ Core
5. Trigonal-lantern dinuclear compounds of diiron(I,II): the synthesis and characterization of two highly paramagnetic Fe2(amidinato)3 species with short metal-metal bonds
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