Thermal Si−C Bond Cleavage of LRhH(SiAr3)(μ-H)(μ-Cl)RhH(SiAr3)L (Ar = C6H5, C6H4F-p; L = P(i-Pr)3) To Give LRhH(μ-SiAr3)(μ-SiAr2)(μ-Cl)RhHL Containing Symmetrically Bridging Triarylsilyl and Diarylsilylene Ligands-Reference-Cited by-同舟云学术

Thermal Si−C Bond Cleavage of LRhH(SiAr3)(μ-H)(μ-Cl)RhH(SiAr3)L (Ar = C6H5, C6H4F-p; L = P(i-Pr)3) To Give LRhH(μ-SiAr3)(μ-SiAr2)(μ-Cl)RhHL Containing Symmetrically Bridging Triarylsilyl and Diarylsilylene Ligands

Published:1998-11-25 Issue:26 Volume:17 Page:5721-5727
ISSN:0276-7333
Container-title:Organometallics
language:en
Short-container-title:Organometallics

Author:

Koizumi Take-aki¹,Osakada Kohtaro¹,Yamamoto Takakazu¹

Affiliation:

1. Research Laboratory of Resources Utilization, Tokyo Institute of Technology, 4259 Nagatsuta, Midori-ku, Yokohama 226-8503, Japan

Publisher

American Chemical Society (ACS)

Subject

Inorganic Chemistry,Organic Chemistry,Physical and Theoretical Chemistry

Link

https://pubs.acs.org/doi/pdf/10.1021/om9804677

Reference70 articles.

1. Photochemical reactions of (.eta.5-pentamethylcyclopentadienyl)dicarbonyliron alkyl and silyl complexes: reversible ethylene insertion into an iron-silicon bond and implications for the mechanism of transition-metal-catalyzed hydrosilation of alkenes

2. Ruthenium-catalysed disproportionation between vinylsilanes and mono-substituted alkenes via silyl group transfer

3. Some organometallic chemistry of ruthenium(II)

4. The synthesis of (E)-1,2-disilylethenes from a triorganosilylethene with the aid of Ru3(CO)12 and a hydrosilane

5. Rhodium-catalyzed transsilylation reactions between bis(trimethylsilyl)ethyne and hexyldimethylsilane

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