The First Experimental Test of the Hypothesis that Enzymes Have Evolved To Enhance Hydrogen Tunneling
Author:
Affiliation:
1. Contribution from the Department of Chemistry, Colorado State University, Fort Collins, Colorado 80523
Publisher
American Chemical Society (ACS)
Subject
Colloid and Surface Chemistry,Biochemistry,General Chemistry,Catalysis
Link
https://pubs.acs.org/doi/pdf/10.1021/ja030120h
Reference79 articles.
1. Enzyme Catalysis: Beyond Classical Paradigms
2. Evidence for Quantum Mechanical Tunneling in the Coupled Cobalt−Carbon Bond Homolysis−Substrate Radical Generation Reaction Catalyzed by Methylmalonyl-CoA Mutase
3. The experimental manifestations of corner-cutting tunneling
4. [14] Hydrogen tunneling in enzyme catalysis
5. Quantum Mechanics/Molecular Mechanics Studies of Triosephosphate Isomerase-Catalyzed Reactions: Effect of Geometry and Tunneling on Proton-Transfer Rate Constants
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