Room Temperature Cyclopentadiene Elimination Reaction for the Synthesis of Diethylgallium−Amides, −Phosphides, and −Thiolates. Crystal and Molecular Structures of [Et2GaP(t-Bu)2]2 and [Et2GaS(SiPh3)]2
Author:
Affiliation:
1. Department of Chemistry, State University of New York at Buffalo, Buffalo, New York 14260
Publisher
American Chemical Society (ACS)
Subject
Inorganic Chemistry,Organic Chemistry,Physical and Theoretical Chemistry
Link
https://pubs.acs.org/doi/pdf/10.1021/om960284p
Reference37 articles.
1. 446. Trimethylgallium. Part I. The relative stabilities of its co-ordination compounds with the methyl derivatives of groups VBand VIB, and the thermal decomposition of some trimethylgallium–amine complexes
2. Cis-trans isomerization and structure of dimeric [Me2Ga(.mu.-NH-tert-Bu)]2
3. 36. Trimethylgallium. Part III. Reaction with diphenylphosphine and -arsine
4. 591. Trimethylgallium. Part V. The reactions of trimethylaluminium, -gallium, and -indium with some primary and secondary phosphines and arsines
5. Use of Me2Ga(C5H5) to prepare (Me2GaERR')n (E = N, P) at or below room temperature and the crystal and molecular structure of [Me2GaP(Me)(Ph)]3
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