A Novel Tandem Cyclization of 2,7- or 2,8-Bis-Unsaturated Esters Mediated by (η2-Propene)TiX2 (X = Cl or O-i-Pr). A Facile Construction of Bicyclo[3.3.0]octane, -[4.3.0]nonane, and -[3.1.0]hexane Skeletons
Author:
Affiliation:
1. Department of Biomolecular Engineering Tokyo Institute of Technology, 4259 Nagatsuta-cho Midori-ku, Yokohama, Kanagawa 226, Japan
Publisher
American Chemical Society (ACS)
Subject
Colloid and Surface Chemistry,Biochemistry,General Chemistry,Catalysis
Link
https://pubs.acs.org/doi/pdf/10.1021/ja961928n
Reference14 articles.
1. Synthetic application of titanabicycles generated from 1,6- or 1,7-dienes, enynes, and diynes and (ν2-propene)Ti(O-i-Pr)2
2. Intramolecular cyclization of conjugated diene and acetylene with (η2-propene)Ti(O-i-Pr)2. Generation and reaction of titanabicycles having an allyltitanium moiety
3. The tandem insertion of trimethylsilylcyanide and alkenes, alkynes, isocyanates or ketones into zirconacyclo-pentanes and -pentenes
4. Catalytic Diastereoselective Synthesis of Cis-1,2-Disubstituted Cyclopropanols from Esters Using a Vicinal Dicarbanion Equivalent
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