Intramolecular Geminal and Vicinal Element Effects in Substitution of Simple Bromo(chloro)alkenes by Methoxide and Thiolate Ions. An Example of a Single Step Substitution?-Reference-Cited by-同舟云学术

Intramolecular Geminal and Vicinal Element Effects in Substitution of Simple Bromo(chloro)alkenes by Methoxide and Thiolate Ions. An Example of a Single Step Substitution?

Published:1997-11-01 Issue:23 Volume:62 Page:8049-8057
ISSN:0022-3263
Container-title:The Journal of Organic Chemistry
language:en
Short-container-title:J. Org. Chem.

Author:

Beit-Yannai Michal¹,Rappoport Zvi¹,Shainyan Bagrat A.¹,Danilevich Yuri S.¹

Affiliation:

1. Department of Organic Chemistry and The Minerva Center of Computational Quantum Chemistry, the Hebrew University, Jerusalem 91904, Israel, and Irkutsk Institute of Organic Chemistry, Siberian Division of the Russian Academy of Sciences, 1 Favorskii Str., 664033 Irkutsk, Russia

Publisher

American Chemical Society (ACS)

Subject

Organic Chemistry

Link

https://pubs.acs.org/doi/pdf/10.1021/jo9709357

Reference42 articles.

1. The “Element Effect” as a Criterion of Mechanism in Activated Aromatic Nucleophilic Substitution Reactions1,2

2. Nucleophilic reactions at vinylic center. 27. Vinylic substitution of 1,2-dibromo-1,2-difluoroethylene and tribromofluoroethylene. An intramolecular kBr/kF element effect and apparent inversion of configuration in SNV reactions

3. Nucleophilic vinylic substitution. A single- or a multi-step process?

4. Reactions Involving Bimolecular Nucleophilic Substitution at a Vinyl Centre

5. Fluoro olefins. IV. Stereochemistry of nucleophilic displacement of chloride ion on .beta.-substituted 1-chloroperfluoro olefins

Cited by 24 articles. 订阅此论文施引文献订阅此论文施引文献，注册后可以免费订阅5篇论文的施引文献，订阅后可以查看论文全部施引文献

1. Dualism of Ion-Pairing Effects in Nucleophilic Vinylic Substitution with Transition-Metal Carbonyl Anions;ChemPlusChem;2013-08-19

2. Nucleophilic substitution at the halogen atom (halogenophilic reactions);Russian Chemical Reviews;2012-04-30

3. Transformations of 2-alkylidene-4-oxothiazolidine vinyl bromides initiated by bromophilic attack of neutral and anionic nucleophiles;Tetrahedron;2010-08

4. Recent Advances in Our Mechanistic Understanding of SNV Reactions;Accounts of Chemical Research;2009-06-12

5. Nucleophilicity of metal carbonyl anions in vinylic substitution reactions;Journal of Physical Organic Chemistry;2008-03