Generation of Perfluoropolyphenylene Oligomers via Carbon−Fluorine Bond Activation by Cp2Zr(C6F5)2: A Dual Mechanism Involving a Radical Chain and Release of Tetrafluorobenzyne
Author:
Affiliation:
1. Contribution from the Department of Chemistry, University of Rochester, Rochester, New York 14627
Publisher
American Chemical Society (ACS)
Subject
Colloid and Surface Chemistry,Biochemistry,General Chemistry,Catalysis
Link
https://pubs.acs.org/doi/pdf/10.1021/ja991805d
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1. Reactions of uranium complex (MeC5H4)3U(t-Bu): intermolecular fluorine atom abstraction from fluorocarbons including saturated perfluorocarbons
2. Oxidatively induced reductive elimination. A novel titanium complex resulting from C–F bond activation
3. Selective room temperature hydrogenolysis of aromatic fluorocarbons mediated by a low-valent zirconium complex
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