Elimination Reactions of Aryl Phenylacetates Promoted by R2NH/R2NH2+ in 70 mol MeCN(aq). Effect of the β-Phenyl Group on the Ketene-Forming Transition State-Reference-Cited by-同舟云学术

Elimination Reactions of Aryl Phenylacetates Promoted by R2NH/R2NH2+ in 70 mol MeCN(aq). Effect of the β-Phenyl Group on the Ketene-Forming Transition State

Published:2000-02-01 Issue:4 Volume:65 Page:1239-1242
ISSN:0022-3263
Container-title:The Journal of Organic Chemistry
language:en
Short-container-title:J. Org. Chem.

Author:

Cho Bong Rae¹,Kim Yong Kwan¹,Seung Yoon Je¹,Kim Ju Chang¹,Pyun Sang Yong¹

Affiliation:

1. Department of Chemistry, Division of Chemistry and Molecular Engineering, Korea University, 1-Anamdong, Seoul 136-701, and Department of Chemistry, Pukyong National University, Pusan 608-737, Korea

Publisher

American Chemical Society (ACS)

Subject

Organic Chemistry

Link

https://pubs.acs.org/doi/pdf/10.1021/jo991473v

Reference24 articles.

1. The carbanion mechanism (ElcB) of ester hydrolysis. III. Some structure-reactivity studies and the ketene intermediate

2. Extended ElcB mechanism for ester hydrolysis: allylic substitution via carbanion in ester hydrolysis

3. Nuclear magnetic resonance investigation of geometrical isomerism in the anions of aromatic amino compounds. The "effective size" of a lone electron pair

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