Pentadienyls vs Cyclopentadienyls and Reversal of Metal−Ligand Bonding Affinity with Metal Oxidation State: Synthesis, Molecular Structures, and Electronic Structures of High-Valent Zirconium Pentadienyl Complexes
Author:
Affiliation:
1. Contribution from the Center for Gas-Phase Electron Spectroscopy, Department of Chemistry, The University of Arizona, Tucson, Arizona 85721, and Department of Chemistry, The University of Utah, Salt Lake City, Utah 84112
Publisher
American Chemical Society (ACS)
Subject
Colloid and Surface Chemistry,Biochemistry,General Chemistry,Catalysis
Link
https://pubs.acs.org/doi/pdf/10.1021/ja040123%2B
Reference80 articles.
1. Pentadienyl Ligands: Their Properties, Potential, and Contributions to Inorganic and Organometallic Chemistry
2. New carbon-carbon bond-forming reaction of carbon monoxide: remarkable trialkylation of a carbonyl ligand in a molybdenum pentadienyl complex
3. Zr(C5H5)(6,6-dmch)(PMe3)2, an edge-bridged half-open zirconocene—synthesis, structure, and its reaction with C6H5C2SiMe3
4. Reaction of Chromium(III) Chloride with the Cycloheptadienyl Anion: Susceptibility of Edge Bridges To C−H Activation Reactions
5. Bis(allyl)nickel and bis(pentadienyl)iron as precursors for the synthesis of tetrakis(trifluorophosphine)nickel tetrakis(difluorophosphine)nickel, and pentakis(trifluorophosphine)nickel
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4. Delocalized and localized donating–accepting Mn–C interactions in half-sandwich cyclopentadienyl and pentadienyl complexes;Dalton Transactions;2017
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