Correlation of the Rates of Solvolysis of the Benzhydryldimethylsulfonium Ion. Application of the Aromatic Ring Parameter1

Author:

Kevill Dennis N.1,Anderson Steven W.1,Ismail Norsaadah HJ1

Affiliation:

1. Department of Chemistry, Northern Illinois University, DeKalb, Illinois 60115-2862

Publisher

American Chemical Society (ACS)

Subject

Organic Chemistry

Reference49 articles.

1. Brief summaries of portions of this work have appeared previously:  (a) Kevill, D. N.; Anderson, S. W.; Fujimoto, E. K. InNucleophilicity; Harris, J. M.; McManus, S. P., Eds.; Advances in Chemistry Series; American Chemical Society:  Washington, DC, 1987; p 278. (b) Kevill, D. N.; Anderson, S. W.; Ismail, N. HJ; Fujimoto, E. K.Studies Org. Chem.1987,31, 311.

2. Solvolysis of the (p-Methoxybenzyl)dimethylsulfonium Ion. Development and Use of a Scale to Correct for Dispersion in Grunwald-Winstein Plots

3. Essentially solvent-independent rates of solvolysis of the 1-adamantyldimethylsulfonium ion. Implications regarding nucleophilic assistance in solvolyses of tert-butyl derivatives and the NKL solvent nucleophilicity scale

4. The Correlation of Solvolysis Rates

5. The Correlation of Solvolysis Rates and the Classification of Solvolysis Reactions into Mechanistic Categories

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