Formation of Tantalum “Tuck-in” Complexes by Activation of Methyl C−H Bonds in Pentamethylcyclopentadiene Groups by Carbazole Ligation
Author:
Affiliation:
1. Department of Chemistry, 1393 Brown Building, Purdue University, West Lafayette, Indiana 47907-1393
Publisher
American Chemical Society (ACS)
Subject
Inorganic Chemistry,Organic Chemistry,Physical and Theoretical Chemistry
Link
https://pubs.acs.org/doi/pdf/10.1021/om990388a
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1. Titanocene as an intermediate in reactions involving molecular hydrogen and nitrogen
2. A kinetic and mechanistic study of the thermolysis of bis(pentamethylcyclopentadienyl)dimethyltitanium(IV)
3. Di-.mu.-oxo-(.eta.1:.eta.5-1,2,3,4-tetramethyl-5-methylene-1,3-cyclopentadiene)-bis[(.eta.-pentamethylcyclopentadienyl)titanium], (.mu.-0)2[.mu.-[.eta.1:.eta.5-C5(CH2)(CH3)4]][Ti(.eta.5-C5(CH3)5)]]2, a complex containing a bridging tetramethylmethylenecyclopentadienyl ligand
4. Intramolecular thermolytic carbon-hydrogen activation processes. Solid-state structural characterization of a mononuclear .eta.6-Me4C5CH2 zirconium complex and a mechanistic study of its formation from (Me5C5)2Zr(C6H5)2
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