Cooling of Melts:  Kinetic Stabilization and Polymorphic Transitions in the KInSnSe4 System

Author:

Hwang Seong-Ju1,Iyer Ratnasabapathy G.1,Trikalitis Pantelis N.1,Ogden Andrew G.1,Kanatzidis Mercouri G.1

Affiliation:

1. Department of Chemistry, Michigan State University, East Lansing, Michigan 48824

Publisher

American Chemical Society (ACS)

Subject

Inorganic Chemistry,Physical and Theoretical Chemistry

Reference8 articles.

1. Molten alkali-metal polychalcogenides as reagents and solvents for the synthesis of new chalcogenide materials

2. New directions in synthetic solid state chemistry: chalcophosphate salt fluxes for discovery of new multinary solids

3. β-KMP2Se6 (M = Sb, Bi):  Kinetically Accessible Phases Obtained from Rapid Crystallization of Amorphous Precursors

4. (a)α-KInSnSe4was prepared from a stoichiometric mixture of K2Se, In, Sn, and Se that was sealed under vacuum (∼2 × 10-4mbar) in a fused silica tube. Well-formed yellow needle-shaped crystals ofα-KInSnSe4suitable for single-crystal X-ray investigation were obtained by forming a melt at 850 °C and cooling at −10 °C/min to room temperature.

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