Reactivity of Silyl-Substituted Allyl Compounds with Group 4, 5, 9, and 10 Metals: Routes to η3-Allyls, Alkylidenes, and sec-Alkyl Carbocations
Author:
Affiliation:
1. Wolfson Materials and Catalysis Centre, School of Chemical Sciences, University of East Anglia, Norwich NR4 7TJ, U.K.
Publisher
American Chemical Society (ACS)
Subject
Inorganic Chemistry,Organic Chemistry,Physical and Theoretical Chemistry
Link
https://pubs.acs.org/doi/pdf/10.1021/om0491692
Reference57 articles.
1. Allyl-Transition Metal Systems
2. Dynamics of solvated lithium(+) within exo,exo-[1,3-bis(trimethylsilyl)allyl]lithium N,N,N',N'-tetramethylethylenediamine complex
3. Novel α,ω-bis(trialkylsilyl)-allyl and -1-azapentadienyl ligands; structures of [Li{η3-CH(CHSiMe2But)2}(tmen)], [Li{N(SiMe3)CBut(CH)3SiMe2But}(tmen)] and [K{η4-N(SiMe2But)CBut(CH)3SiMe2But}]∞
4. Synthesis and structures of some silylallyl-lithium or -potassium complexes
5. Reactions of silylallyl-lithium or -potassium compounds with ButCN; synthesis and structures of [M{N(SiMe2R)C(But)(CH)3SiMe2But}] [M = Li(tmen), R = Me; or M = K, R = But], [Li{N(SiMe3)C(But)>>CCHC(SiMe3)(CH2)2C>>H2}(tmen)] and [{Li[NC(But)>>CHCHC(SiMe3)(CH2)2C>>H2]}4] (tmen = Me2NCH2CH2NMe2)
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