On the Role of Tetramethylammonium Cation and Effects of Solvent Dynamics on the Stability of the Cage-like Silicates Si6O156- and Si8O208- in Aqueous Solution. A Molecular Dynamics Study-Reference-Cited by-同舟云学术

On the Role of Tetramethylammonium Cation and Effects of Solvent Dynamics on the Stability of the Cage-like Silicates Si6O156- and Si8O208- in Aqueous Solution. A Molecular Dynamics Study

Published:2005-12-15 Issue:2 Volume:128 Page:596-606
ISSN:0002-7863
Container-title:Journal of the American Chemical Society
language:en
Short-container-title:J. Am. Chem. Soc.

Author:

Caratzoulas Stavros¹,Vlachos Dionisis G.¹,Tsapatsis Michael¹

Affiliation:

1. Contribution from the Department of Chemical Engineering, University of Delaware, Newark, Delaware 19716, and Department of Chemical Engineering and Materials Science, University of Minnesota, 421 Washington Avenue SE, Minneapolis, Minnesota 55455

Publisher

American Chemical Society (ACS)

Subject

Colloid and Surface Chemistry,Biochemistry,General Chemistry,Catalysis

Link

https://pubs.acs.org/doi/pdf/10.1021/ja0561136

Reference41 articles.

1. Molecular Dynamics Studies on the Role of Tetramethylammonium Cations in the Stability of the Silica Octamers Si8 in Solution

2. Structural links between zeolite-type and clathrate hydrate-type materials: Redetermination of the crystal structure of [N(CH3)4]8[Si8O20]·65H2O by single-crystal X-ray diffraction and variable-temperature MAS NMR spectroscopy

3. [NPhMe3]6[Si8O18(OH)2]·38.7H2O and [NBnMe3]8[Si8O20]·53.6H2O, heteronetwork clathrates with three-dimensional mixed silicatewater host structures and channel systems

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