Hydride Abstraction from η3-Allylic Molybdenum Complexes Exploring Various Diaryl Carbenium Ion Precursors. A Study toward Enantioselective Hydride Abstraction
Author:
Affiliation:
1. Department of Organic Chemistry 1, Chemical Center, Lund University, P.O. Box 124, S-221 00 Lund, Sweden, and Department of Synthetic Chemistry, ACADIA Pharmaceuticals A/S, Fabriksparken 58, DK-2600 Glostrup, Denmark
Publisher
American Chemical Society (ACS)
Subject
Inorganic Chemistry,Organic Chemistry,Physical and Theoretical Chemistry
Link
https://pubs.acs.org/doi/pdf/10.1021/om011016g
Reference22 articles.
1. Stereo- and Regiocontrolled Construction of Trisubstituted Piperidines Using a TpMo(CO)2(Dihydropyridine) Scaffold (Tp = Hydridotrispyrazolylborate)
2. Enantiospecific synthesis by transformations of chiral pool-derived metal .pi.-complexes. A strategy for the introduction of substituents on a pyranose-derived lateral .pi.-ligand either syn or anti to the coordinating metal
3. Synthesis and reactions of enantiomerically pure molybdenum .pi.-complexes of 2H-pyran. A general approach to the enantiospecific synthesis of cis-2,5-disubstituted-5,6-dihydro-2H-pyrans and cis-2,6-disubstituted tetrahydropyrans
4. Enantioselective Hydride Abstraction in Organic Substrates: A Novel Use for Chiral Carbenium Ions
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