Global Diastereoconvergence in the Ireland–Claisen Rearrangement of Isomeric Enolates: Synthesis of Tetrasubstituted α-Amino Acids-Reference-Cited by-同舟云学术

Global Diastereoconvergence in the Ireland–Claisen Rearrangement of Isomeric Enolates: Synthesis of Tetrasubstituted α-Amino Acids

Published:2020-12-15 Issue:52 Volume:142 Page:21938-21947
ISSN:0002-7863
Container-title:Journal of the American Chemical Society
language:en
Short-container-title:J. Am. Chem. Soc.

Author:

Fulton Tyler J.¹,Cusumano Alexander Q.¹,Alexy Eric J.¹,Du Yun E.¹,Zhang Haiming²^ORCID,Houk K. N.³^ORCID,Stoltz Brian M.¹^ORCID

Affiliation:

1. The Warren and Katharine Schlinger Laboratory for Chemistry and Chemical Engineering, Division of Chemistry and Chemical Engineering, California Institute of Technology, Pasadena, California 91125, United States

2. Small Molecule Process Chemistry, Genentech, Inc., South San Francisco, California 94080, United States

3. Department of Chemistry and Biochemistry, University of California, Los Angeles, California 90095, United States

Funder

Division of Chemistry

Gordon and Betty Moore Foundation

National Institute of General Medical Sciences

National Science Foundation

California Institute of Technology

Publisher

American Chemical Society (ACS)

Subject

Colloid and Surface Chemistry,Biochemistry,General Chemistry,Catalysis

Link

https://pubs.acs.org/doi/pdf/10.1021/jacs.0c11480

Reference38 articles.

1. Claisen rearrangement of allyl esters

2. The ester enolate Claisen rearrangement. Stereochemical control through stereoselective enolate formation

3. Synthesis of Enantioenriched Vicinal Tertiary and Quaternary Carbon Stereogenic Centers within an Acyclic Chain

4. Recent advances in asymmetric synthesis using chiral lithium amide bases

5. Acyclic Stereocontrol in the Ireland–Claisen Rearrangement of α-Branched Esters

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