Structure and Reactivity of trans-Bis[2-(2-chloroethyl)pyridine]palladium Chloride (1). A Study on the Elimination Reaction of 1 and 2-(2-Chloroethyl)pyridine Induced by Quinuclidine in Acetonitrile
Author:
Affiliation:
1. Dipartimento di Chimica, Università degli Studi di Perugia, via Elce di Sotto 8, 06123 Perugia, Italy, and LSDSMS (UMR 5636 CNRS), case courrier 14, Institut Gerhardt, Université Montpellier 2, F-34095 Montpellier Cedex 5, France
Publisher
American Chemical Society (ACS)
Subject
Organic Chemistry
Link
https://pubs.acs.org/doi/pdf/10.1021/jo051324e
Reference27 articles.
1. Mechanism and proton activating factors in base-induced β-elimination reactions of N-[2-(4-pyridyl)ethyl]quinuclidinium and N-[2-(2-pyridyl)ethyl]quinuclidinium salts †
2. Mechanism and proton activating factors in base-induced β-elimination reactions of 2-(2-chloroethyl)pyridine †
3. Catalysis of the β-Elimination of HF from Isomeric 2-Fluoroethylpyridines and 1-Methyl-2-fluoroethylpyridinium Salts. Proton-Activating Factors and Methyl-Activating Factors as a Mechanistic Test To Distinguish between Concerted E2 and E1cb Irreversible Mechanisms
4. Use of solvent isotope effect to identify an intermediate carbanion in the β-elimination reactions from N-[2-(4-pyridyl)ethyl]quinuclidinium and N-[2-(2-pyridyl)ethyl]quinuclidinium induced by acetohydroxamate/acetohydroxamic acid buffers
5. Mechanisms of Acid−Base Catalysis of β-Elimination Reactions in Systems Activated by a Pyridine Ring
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