Dimolybdenum and Ditungsten Cyclopentadienyl Carbonyls with Electron-Rich Phosphido Bridges. Synthesis of the Hydrido Phosphido Complexes [M2Cp2(μ-H)(μ-PRR‘)(CO)4] and Unsaturated Bis(phosphido) Complexes [M2Cp2(μ-PR2)(μ-PR‘R‘ ‘)(CO)x] (x = 1, 2; R, R‘, R‘ ‘ = Et, Cy, tBu)
Author:
Affiliation:
1. Departamento de Química Orgánica e Inorgánica/IUQOEM, Universidad de Oviedo, E-33071 Oviedo, Spain
Publisher
American Chemical Society (ACS)
Subject
Inorganic Chemistry,Organic Chemistry,Physical and Theoretical Chemistry
Link
https://pubs.acs.org/doi/pdf/10.1021/om020573f
Reference40 articles.
1. [Mo2(η5-C5H5)2(μ-PPh2)(CO)4], a Reactive 33-Electron Binuclear Radical
2. Reactive Hydroxo and Hydroxycarbyne Cyclopentadienyl Complexes. Proton Transfer and Oxidative Addition of O−H Bonds at Unsaturated Ditungsten Centers
3. Phosphorus- and Arsenic-Bridged Complexes of Metal Carbonyls. II. Cyclopentadienylnickel, molybdenum, and tungsten Complexes
4. Neutron diffraction studies of the metal-hydrogen-metal bond. I. Symmetric, bent, three-center, two-electron molybdenum-hydrogen-molybdenum bond in .mu.-hydrido-.mu.-dimethylphosphido-bis(.eta.5-cyclopentadienyldicarbonylmolybdenum)
5. Metal carbonyl complexes of phenylphosphine and diphenylphosphine
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