A new example of a palladium-assisted aryl rearrangement. Synthesis and reactivity of (2,3,4-trimethoxy-6-X-phenyl)Pd [X = CHO, CH:N(n-C10H21), CH:NC6H4(NH2)-2, C(O)Me] and (3,4,5-trimethoxy-2-X-phenyl)Pd [X = CHO, CH:NC6H4(NH2)-2] complexes. Crystal and molecular structure of [Pd(.kappa.3-C6H[CH:NC6H4(NH2)-2]-6-(OMe)3-2,3,4)(PPh3)]CF3SO3, [Pd(.kappa.3-C6H[CH:NC6H4(NH2)-2]-2-(OMe)3-3,4,5)(PPh3)]CF3SO3, and [Pd(.kappa.2-C6H[C(O)Me]-6-(OMe)3-2,3,4)(2,9-dimethyl-1,10-phenanthroline)]CF3SO3-Reference-Cited by-同舟云学术

A new example of a palladium-assisted aryl rearrangement. Synthesis and reactivity of (2,3,4-trimethoxy-6-X-phenyl)Pd [X = CHO, CH:N(n-C10H21), CH:NC6H4(NH2)-2, C(O)Me] and (3,4,5-trimethoxy-2-X-phenyl)Pd [X = CHO, CH:NC6H4(NH2)-2] complexes. Crystal and molecular structure of [Pd(.kappa.3-C6H[CH:NC6H4(NH2)-2]-6-(OMe)3-2,3,4)(PPh3)]CF3SO3, [Pd(.kappa.3-C6H[CH:NC6H4(NH2)-2]-2-(OMe)3-3,4,5)(PPh3)]CF3SO3, and [Pd(.kappa.2-C6H[C(O)Me]-6-(OMe)3-2,3,4)(2,9-dimethyl-1,10-phenanthroline)]CF3SO3

Published:1993-10 Issue:10 Volume:12 Page:4151-4160
ISSN:0276-7333
Container-title:Organometallics
language:en
Short-container-title:Organometallics

Author:

Vicente Jose,Abad Jose Antonio,Gil-Rubio Juan,Jones Peter G.,Bembenek Eberhard

Publisher

American Chemical Society (ACS)

Subject

Inorganic Chemistry,Organic Chemistry,Physical and Theoretical Chemistry

Link

https://pubs.acs.org/doi/pdf/10.1021/om00034a059

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