Stereoselective Synthesis of Atropisomeric Korupensamines A and B Utilizing Planar Chiral Arene Chromium Complex

Author:

Watanabe Takashi1,Tanaka Yoshie1,Shoda Ryohei1,Sakamoto Ryota1,Kamikawa Ken1,Uemura Motokazu1

Affiliation:

1. Department of Chemistry, Faculty of Integrated Arts and Science, Osaka Prefecture University, Sakai, Osaka 599-8531, Japan, and Research Institute for Advanced Science and Technology, Osaka Prefecture University, Sakai, Osaka 599-8570, Japan

Publisher

American Chemical Society (ACS)

Subject

Organic Chemistry

Reference76 articles.

1. For some representative reviews:  (a) Bringmann, G.; Walter, R.; Weirich, R.Angew.Chem.Int. Ed. Engl.1990,29, 977. (b) Lutomski, K. A.; Meyers, A. I. Asymmetric Synthesis via Chiral Oxazolines.InAsymmetric Synthesis; Morrison, J. D., Ed.; Academic Press, Inc.  New York, 1984; Vol. 3, p 213. (c) Gant, T. G. Meyers, A. I.Tetrahedron1994,50, 2297. (d) Bringmann, G.; Menche, D.Acc. Chem. Res.2001,34, 615. (e) Lloyd-Williams, P.; Giralt, E.Chem. Soc. Rev.2001,30, 145.

2. Enantioselective synthesis of binaphthyls via nucleophilic aromatic substitution on chiral oxazolines

3. Oxazoline-mediated biaryl coupling reactions. Stereocontrolled synthesis of 2,2′,6,6′-tetrasubstituted biphenyls.

4. Asymmetric total synthesis of dibenzocyclooctadiene lignans (-)-schizandrin and (-)-isoschizandrin. Structure revision of (+)-isoschizandrin

5. Synthesis of a model 22-membered AB-C-O-D ring of vancomycin containing biaryl and biaryl ether linkages

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