High-Temperature Raman Investigation of Concentrated Sulfuric Acid Mixtures:  Measurement of H-Bond ΔH Values between H3O+ or H5O2+ and HSO4-

Author:

Walrafen G. E.1,Yang W.-H.1,Chu Y. C.1

Affiliation:

1. Department of Chemistry, University of Kansas, Lawrence, Kansas 66045-0046

Publisher

American Chemical Society (ACS)

Subject

Physical and Theoretical Chemistry

Reference26 articles.

1. The Thermodynamic Properties of Aqueous Sulfuric Acid Solutions and Hydrates from 15 to 300°K.1

2. The data of reference 1 as treated in Lewis, G. N.; Randall, M.Thermodynamics and the Free Energy of Chemical Substances; McGraw-Hill:  New York, 1923; p 95, Table 7, were subjected to least-squares analysis using a seventh-degree polynomial. Data of reference 2 were subjected to least-squares analysis using a fifth-degree polynomial.

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