Nucleophilic Addition to the η2-Alkyne Ligand in [CpFe(CO)2(η2-R−C⋮C−R)]+. Dependence of the Alkenyl Product Stereochemistry on the Basicity of the Nucleophile-Reference-Cited by-同舟云学术

Nucleophilic Addition to the η2-Alkyne Ligand in [CpFe(CO)2(η2-R−C⋮C−R)]+. Dependence of the Alkenyl Product Stereochemistry on the Basicity of the Nucleophile

Published:2001-05-23 Issue:13 Volume:20 Page:2736-2750
ISSN:0276-7333
Container-title:Organometallics
language:en
Short-container-title:Organometallics

Author:

Akita Munetaka¹,Kakuta Satoshi¹,Sugimoto Shuichiro¹,Terada Masako¹,Tanaka Masako¹,Moro-oka Yoshihiko¹

Affiliation:

1. Chemical Resources Laboratory, Tokyo Institute of Technology, 4259 Nagatsuta, Midori-ku, Yokohama 226-8503, Japan

Publisher

American Chemical Society (ACS)

Subject

Inorganic Chemistry,Organic Chemistry,Physical and Theoretical Chemistry

Link

https://pubs.acs.org/doi/pdf/10.1021/om010095t

Reference56 articles.

1. (a) Reger, D. L.Acc.Chem.Res.1988,21, 229, and references therein.

2. The cis addition of hydride to .eta.2-alkyne complexes by initial reaction at an .eta.5-cyclopentadienyl (.eta.5-C5H5) ring. Crystal and molecular structure of the carbonyl-.eta.5-cyclopentadienyliron complex (.eta.5-C5H5)FeCO(PPh3)[.eta.1-E-C(CO2Et):CHMe]

3. New CpFeCO[P(OPh)3](.eta.1-alkenyl) and CpFeCO[P(OPh)3](.eta.1-alkenylacyl) complexes. Crystal and molecular structure of CpFeCO[P(OPh)3][.eta.1-(E)-COC(CH2OMe):C(Me)Ph] and an NMR method to assign alkenyl ligand structure

4. Synthesis of Cyclopentadienyl(1,4-diisopropyl-1,3-diazabutadiene)(L)ruthenium Trifluoromethanesulfonate (L = Alkene, Alkyne, CO, Pyridine, PPh3). X-ray Structure of [(.eta.5-C5H5)Ru(iPr-DAB)(.eta.2-propene)][CF3SO3]

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