Photoelectron Spectra of Trimethylphosphine-Substituted Tungsten Carbonyls: Ligand Field Effects, Ligand Additivity Effects, and Core−Valence Ionization Correlations
Author:
Affiliation:
1. Department of Chemistry, University of Western Ontario, London, Ontario, Canada N6A 5B7, and Canadian Synchrotron Radiation Facility, University of WisconsinMadison, Stoughton, Wisconsin 53589
Publisher
American Chemical Society (ACS)
Subject
Inorganic Chemistry,Physical and Theoretical Chemistry
Link
https://pubs.acs.org/doi/pdf/10.1021/ic9904687
Reference50 articles.
1. Photoelectron spectra of substituted chromium, molybdenum, and tungsten pentacarbonyls. Relative .pi.-acceptor and .sigma.-donor properties of various phosphorus ligands
2. Ligand additivity in the valence photoelectron spectroscopy of phosphine-substituted molybdenum carbonyls
3. Photoelectron study of additivity and ligand field effects on the tungsten 5d orbitals in [W(CO)6-n(PR3)n] compounds
4. Spectroscopic study of the effect of methyl and phenyl substituents on the basicity of phosphine ligands in tungsten carbonyl derivatives
5. Photoelectron spectra of complexes [W(CO)5(PMenPh3-n)]: triphenylphosphine is a stronger base than trimethylphosphine
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