Oxidatively Induced Carbonylation and Cyclization of Ruthenium(II) Vinyl−Olefin Complexes Prepared via Allyl/Alkyne Coupling
Author:
Affiliation:
1. Department of Chemistry, University of Alberta, Edmonton, Alberta, T6G 2G2 Canada
Publisher
American Chemical Society (ACS)
Subject
Inorganic Chemistry,Organic Chemistry,Physical and Theoretical Chemistry
Link
https://pubs.acs.org/doi/pdf/10.1021/om000407c
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1. Reaction of (.eta.5-C5H5)(CO)2Fe(2-norbornyl) complexes and triphenylmethyl tetrafluoroborate: competitive .beta.-elimination and redox-catalyzed migratory carbonyl insertion
2. Insertion of hexafluoro-2-butyne into a palladium bond
3. A novel route to .alpha.-methylenecyclopentenones: a high yield synthesis of methylenomycin B
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