Reactive Intermediates Formed During Olefin Polymerization by Methylalumoxane-Activated ansa-Zirconocene Catalysts: Identification of a Chain-Carrying Intermediate by NMR Methods
Author:
Affiliation:
1. Boreskov Institute of Catalysis, Siberian Branch of Russian Academy of Science, Pr. Lavrentieva 5, Novosibirsk, RU-630090, Russia, and Fachbereich Chemie, Universität Konstanz, D-78457 Konstanz, Germany
Publisher
American Chemical Society (ACS)
Subject
Colloid and Surface Chemistry,Biochemistry,General Chemistry,Catalysis
Link
https://pubs.acs.org/doi/pdf/10.1021/ja909157r
Reference24 articles.
1. Reviews:
2. Selectivity in Propene Polymerization with Metallocene Catalysts
3. Cocatalysts for Metal-Catalyzed Olefin Polymerization: Activators, Activation Processes, and Structure−Activity Relationships
4. Kinetic and mechanistic aspects of metallocene polymerisation catalysts
5. Direct Observation of Insertion Events at rac-(C2H4(1-indenyl)2)Zr(MeB(C6F5)3)−Polymeryl Intermediates: Distinction between Continuous and Intermittent Propagation Modes
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